on fire; ablaze: The house was all aflame.
eager and excited: I was aflame with curiosity.

1545–55; a-1 + flame Unabridged
Based on the Random House Dictionary, © Random House, Inc. 2014.
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World English Dictionary
aflame (əˈfleɪm)
adv, —adj
1.  in flames; ablaze
2.  deeply aroused, as with passion: he was aflame with desire
3.  (of the face) red or inflamed

Collins English Dictionary - Complete & Unabridged 10th Edition
2009 © William Collins Sons & Co. Ltd. 1979, 1986 © HarperCollins
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Word Origin & History

1550s, from a- "on" (see a- (1)) + flame (q.v.).
Online Etymology Dictionary, © 2010 Douglas Harper
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Example sentences
As the shadow rises, it breaks into a cloud of tautly ribbed sail, aflame in the tropical sun.
He had meant to stay longer, he said, but his body was aflame with pain.
Thus, the heat transfer from the gaseous flame to the condensed fuel usually is an essential process to sustain aflame spread.
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