chagrin

[shuh-grin]
noun
1.
a feeling of vexation, marked by disappointment or humiliation.
verb (used with object), chagrined or chagrinned, chagrining or chagrinning.
2.
to vex by disappointment or humiliation: The rejection of his proposal chagrined him deeply.
3.
Obsolete, shagreen ( def 1 ).

Origin:
1650–60; < French < ?

unchagrined, adjective


1. See shame.
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World English Dictionary
chagrin (ˈʃæɡrɪn)
 
n
1.  a feeling of annoyance or mortification
 
vb
2.  to embarrass and annoy; mortify
 
[C17: from French chagrin, chagriner, of unknown origin]
 
'chagrined
 
adj

Collins English Dictionary - Complete & Unabridged 10th Edition
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Etymonline
Word Origin & History

chagrin
1656, "melancholy," from Fr. (15c.), via Angevin dial. chagraigner "sadden" from O.Fr. graignier "grief, vexation," from graim "sorrowful," from a Gmc. source, perhaps Frank. *gram (cf. O.H.G. gram "angry, fierce"). Modern sense is 1716.
Online Etymology Dictionary, © 2010 Douglas Harper
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Example sentences
They waited in the hall, looking chagrined and angry.
With legs crossed and mouths pursed, they appear chagrined by what was meant to
  be a delicious fantasy.
The group started out sluggishly, as if a bit chagrined.
He is chagrined at the basic historical facts he was once taught but can no
  longer remember or, worse, never knew to begin with.
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