Is it ensure, insure, or assure?
"thick block" of something, 1690s, probably a nasalized variant of chuck (n.1) "cut of meat;" meaning "large amount" is 1883, American English.
"to throw," 1835, American English, from chunk (n.) or by similar mutation from chuck (v.1). Related: Chunked; chunking.
To throw; chuck (1830s+)