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free-electron model of metals

in solid-state physics, representation of a metallic solid as a container filled with a gas composed of free electrons (i.e., those responsible for high electrical and thermal conductivity). The free electrons, considered identical to the outermost, or valence, electrons of free metal atoms, are presumed to be moving independently of one another throughout the entire crystal

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Encyclopedia Britannica, 2008. Encyclopedia Britannica Online.
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