the ability of certain organic compounds to react in isomeric structures that differ from each other in the position of a hydrogen atom and a double bond.
Main Entry: tau·tom·er·ism Pronunciation: to-'täm-&-"riz-&m Function: noun : isomerism in which the isomers change into oneanother with great ease so that they ordinarily exist together in equilibrium
tautomerism tau·tom·er·ism (tô-tŏm'ə-rĭz'əm) n. Chemical isomerism in which the isomeric forms differ little, usually only in the position of a hydrogen atom, and are able to exist in equilibrium and react with each other.