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transannular

[trans-an-yuh-ler, tranz-] /trænsˈæn yə lər, trænz-/
adjective, Chemistry
1.
of or pertaining to tautomerism in cyclic compounds that is characterized by the migration of an atom or group from one position in the ring to another.
Origin
Dictionary.com Unabridged
Based on the Random House Dictionary, © Random House, Inc. 2014.
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