1637, "having two modes of existence, of doubtful nature," from Gk.
amphibia, neut. pl. of
amphibios, from
amphi- "of both kinds" +
bios "life" (see
bio-). Formerly used by zoologists to describe all sorts of combined natures (including otters and seals), the biological sense "class of animals between fishes and reptiles that live both on land and in water," and the noun derivative, first recorded 1835.
Amphibia was used in this sense from 1609 and has been a zoological classification since c.1819.
Amphibious with ref. to motorized vehicles dates from 1915.