courteous, gracious, and having a sophisticated charm: a debonair gentleman.
jaunty; carefree; sprightly.
Also, debonaire, debonnaire.

1175–1225; Middle English debone(i)re < Anglo-French; Old French debonaire, orig. phrase de bon aire of good lineage

debonairly, adverb
debonairness, noun

1. urbane, suave, elegant, polished. Unabridged
Based on the Random House Dictionary, © Random House, Inc. 2014.
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World English Dictionary
debonair or debonnaire (ˌdɛbəˈnɛə)
1.  suave and refined
2.  carefree; light-hearted
3.  courteous and cheerful; affable
[C13: from Old French debonaire, from de bon aire having a good disposition]
debonnaire or debonnaire
[C13: from Old French debonaire, from de bon aire having a good disposition]
debo'nairly or debonnaire
debo'nairness or debonnaire

Collins English Dictionary - Complete & Unabridged 10th Edition
2009 © William Collins Sons & Co. Ltd. 1979, 1986 © HarperCollins
Publishers 1998, 2000, 2003, 2005, 2006, 2007, 2009
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Word Origin & History

early 13c., from O.Fr., from de bon' aire "of good race," originally used of hawks, hence, "thoroughbred" (opposite of Fr. demalaire). Used in M.E. to mean "docile, courteous," it became obsolete and was revived with an altered sense of "pleasant, affable" (1680s).
Online Etymology Dictionary, © 2010 Douglas Harper
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Example sentences
You assume the role of a villain instead of the debonair agent 007.
Jack is looking debonair in a bow tie and velvet smoking jacket.
Only the most far-gone misanthrope could help liking him — his debonair
  good humor, open-faced charm.
The smile he then flashed was debonair, knowing and a little mischievous.
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