dishabituate

[dis-huh-bich-oo-eyt]

verb (used with object), dis·ha·bit·u·at·ed, dis·ha·bit·u·at·ing.

to cause to be no longer habituated or accustomed.

Origin:
1865–70; dis-¹ + habituate

Dictionary.com Unabridged
Based on the Random House Dictionary, © Random House, Inc. 2012.
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Dishabituate has a plethora of syllables.

So is supercalifragilisticexpialidocious. Does it mean:

the estimation of something as valueless (encountered mainly as an example of one of the longest words in the English language).

(used as a nonsense word by children to express approval or to represent the longest word in English.)

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dis·ha·bit·u·ate