Encyclopedia
Pr
((Pr), chemical element, rare-earth metal of transition Group IIIb of the periodic table, used as the element in special alloys and, as its oxide, in glasses. Moderately soft, ductile, and malleable, this silvery metal rapidly displaces hydrogen from water and slowly reacts in air, developing a green oxide coating, which chips. For preservation, the metal must be sealed in a plastic covering or kept in mineral oil. Praseodymium was discovered in didymia, a mixture of several rare-earth oxides. From it, by repeated fractional crystallization of ammonium didymium nitrate, Carl Auer von Welsbach separated (1885) salts of the elements praseodymium (the green fraction) and neodymium. Praseodymium occurs in minerals such as monazite and bastnaesite and as one of the products of nuclear fission. Natural praseodymium is all stable isotope praseodymium-141. This element is commercially separated and purified by ion-exchange techniques; the reduction of the fluoride or chloride with calcium is one way in which the metal itself is prepared
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