noun British Informal.
a stylishly dressed, fashionable person, especially one who is or wants to be considered a member of the upper class.

1850–55; perhaps variant of tuft Unabridged
Based on the Random House Dictionary, © Random House, Inc. 2014.
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World English Dictionary
toff (tɒf)
slang (Brit) a rich, well-dressed, or upper-class person, esp a man
[C19: perhaps variant of tuft, nickname for a titled student at Oxford University, wearing a cap with a gold tassel]

Collins English Dictionary - Complete & Unabridged 10th Edition
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Word Origin & History

lower-class British slang for "stylish dresser, member of the smart set," 1851, probably an alteration of tuft, formerly an Oxford Univ. term for a nobleman or gentleman-commoner (1755), in ref. to the gold ornamental tassel worn on the caps of undergraduates at Oxford and Cambridge whose fathers were
peers with votes in the House of Lords.
Online Etymology Dictionary, © 2010 Douglas Harper
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