unaccustomed

[uhn-uh-kuhs-tuhmd]
adjective
1.
not accustomed or habituated: to be unaccustomed to hardships.
2.
unusual; unfamiliar: A brief after-dinner speech is an unaccustomed pleasure.

Origin:
1520–30; un-1 + accustomed

unaccustomedness, noun


2. uncommon, extraordinary, curious, peculiar, unexpected.
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World English Dictionary
unaccustomed (ˌʌnəˈkʌstəmd)
 
adj
1.  (foll by to) not used (to): unaccustomed to pain
2.  not familiar; strange or unusual
 
unac'customedness
 
n

Collins English Dictionary - Complete & Unabridged 10th Edition
2009 © William Collins Sons & Co. Ltd. 1979, 1986 © HarperCollins
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Etymonline
Word Origin & History

unaccustomed
1526, "not customary, unfamiliar," from un- (1) "not" + pp. of accustom. Meaning "not accustomed or habituated" (to) is first attested 1611.
Online Etymology Dictionary, © 2010 Douglas Harper
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Example sentences
The streets are becoming overrun with animals that are unaccustomed to their
  new surroundings.
They could be found in unaccustomed places that summer.
The unaccustomed feels the sensation of being in a panic, in a tempest, in a
  cyclone.
Both being unaccustomed to each other, their relationship is fraught with
  apprehension and fear.
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